Mathematical Modelling of Hydrothermal Carbonization of Biomass Using MATLAB
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This paper presents an original reaction kinetics model as a tool for estimating the carbon yield in hydrothermal carbonization (HTC) of biomass. The kinetics model was developed in MATLAB. The reaction pathways described through a model, in which biomass is converted into solid, liquid and gaseous products. Runge-Kutta method was used to solve the 4 equations derived from the reaction suggestion, through the estimation of 6 Arrhenius kinetics parameters (k1, k2, k3, k4, k5, and k6). The HTC reaction pathway was described through a lumped model, in which biomass is converted into three phase, residual solid, liquid and gaseous products. By choosing the values of k1 and others k values and modelling predictions are in the good of the figure pattern. The k values gave good pattern of figure 3 were k1 = 0.3, k2=0.1, k3=0.3, k4=0.1, k5=0.2, and k6=0.1. They resulted that the biomass conversion was very high about of 90%, carbon content of 39%, liquid content of 24, and gaseous content of 30%.
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Deguchi, S., Tsujii, K., Horikoshi, K. (2008). Crystalline to amorphous transformation of cellulose in hot and compressed water and Its implication for hydrothermal conversion. Green Chem. 10:191 – 196. 10.1039/B713655B. DOI: https://doi.org/10.1039/B713655B
Wang, M.C., Xu,C.B., and Leitch,M.(2009). Liquefaction of cornstalk in hot-compressed phenol water medium to phenolic feedstock for the synthesis of phenol-formaldehyde resin. Bioresour. Technol. 100(7), 2305 – 2307. DOI: https://doi.org/10.1016/j.biortech.2008.10.043
Huang, H.J., Yuan, X.Z., Zeng, G.M., wang, J.Y., Li, H., Zhou,C.F., Pei, X.K., You,Q., Cheng, L. (2011). Thermochemical liquefaction Characteristics of microalgae in sub- and supercritical ethanol. Fuel processing Technology. 92, 147 - 153. DOI: https://doi.org/10.1016/j.fuproc.2010.09.018
Baccile,N., Reboul,J., Blanc,B. et al. 2008. Ecodesign of ordered Mesoporous Materials Obtained with Switchoble Micellar Assemblies. J.German Chemical Society. Doi:10.1002/anie.200802431 DOI: https://doi.org/10.1002/ange.200802431
Pedersen,T.H. Hydrothermal Liquifaction of Biomass and Model compounds. Det Teknisk-Naturavidens kabelige, Fakultet. PhD Thesis, Aalborg Universitet, 2016. Doi: 10.5278/ubu.phd,engoci.00050
Baccile, N., Babonneau, F., Yhomas,B. and Coradin,T. 2009. Introducing ecodesign in silica sol-gel materials. J. Material Chemistry. Issue 45, 2009. DOI: https://doi.org/10.1039/b911123a
Hu,B.,Wang,K.,Wu,L.,Yu,S-H.,Antonietti,M. and Titirici,M-M.2010. Egineering carbon materials from the hydrothermal carbonization Process of Biomass. Advanced Materials, 22(7), 813-828, doi: 10.1002/1dma.200902812. DOI: https://doi.org/10.1002/adma.200902812
Lucian, M.,Piro,G., and Fiori,L. 2018. A Novel Reaction Kinetics Model for Estimating the Carbon Content into Hydrothermal Carbonization Products. Chemical Engineering. Vol. 65, 379-384. doi: 10.3303/CET1865064.
Lucian,M., Volpe, M. and Fiori,L. 2019. Hydrothermal Carbonization Kinetics of Lignocellulosic Agro-Waste: Experimental Data and Modeling. Energies.. Vol. 12, 516-. doi: 10.3390/en12030516. DOI: https://doi.org/10.3390/en12030516

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