Corrosion Inhibition and Adsorption Properties of Ethanolic Extract of Lannea Microcarpa Leaves on Carbon Steel and Zinc Metal in Acidic Medium
Authors
Naziru Alhassan Muhammad
Department of Chemistry, Aliko Dangote University of Science and Technology, Wudil, Kano State, Nigeria (NG)
Abdu Muhammad Bello
Department of Chemistry, Aliko Dangote University of Science and Technology, Wudil, Kano State, Nigeria (NG)
Sani Sharif Bashir
Department of Chemistry, Aliko Dangote University of Science and Technology, Wudil, Kano State, Nigeria (NG)
Umar Yushau
Department of Chemistry, Aliko Dangote University of Science and Technology, Wudil, Kano State, Nigeria (NG)
Rukayya Umar Haruna
Department of Chemistry, Aliko Dangote University of Science and Technology, Wudil, Kano State, Nigeria (NG)
Article Information
DOI: 10.51583/IJLTEMAS.2025.140400026
Subject Category: Chemistry
Volume/Issue: 14/4 | Page No: 260-266
Publication Timeline
Submitted: 2025-05-05
Published: 2025-05-15
Abstract
Abstract: Corrosion of materials such as mild steel and or zinc metal causes big losses in the economy of many countries due to the great amount of funds required in order to be minimized. The aim of the research is to investigate the corrosion of carbon steel and zinc metal in acidic medium using Lannea microcarpa leaves extract by weight loss method. It was observed that the inhibition efficiency increase with temperature for both carbon steel and zinc metal. The adsorption of Lannea microcarpa leaves were found to obey Langmuir isotherm model for zinc metal with R2 value close to unity and that of carbon steel obeys Freundlich isotherm model.
Keywords
Corrosion, Lannea microcarpa, Carbon Steel, Zinc Metal, Langmuir isotherm, Freundlich isotherm
Downloads
References
1. Mustapha, B.I., Khalid, D.K., Naziru, A.M., and Ahmad, B. (2016). Corrosion Inhibition and Adsorption Properties of Prosopis juliflora Leaves Extract for the Corrosion of Mild Steel in 1M HCl Solution. Journal of Scientific Research & Reports, vol 10(3), pp. 1-7. [Google Scholar] [Crossref]
2. Lingjie, Li., Xueping, Z., Jinglei, L., Jianxin, H., Shengta, Z., and Fusheng, P. (2012). Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel. Corrosion Science 63, 82–90. [Google Scholar] [Crossref]
3. Ayse, O.Y., and Gulfeza, K. (2012). Adsorption and inhibition effect of 2-thiohydantoin on mild steel corrosion in 0.1 M HCl. Corrosion Science 58, 86–94. [Google Scholar] [Crossref]
4. Mohammed, A., Amin, A., and Mohamed, M.I. (2011). Corrosion and corrosion control of mild steel in concentrated H2SO4 solutions by a newly synthesized glycine derivative. Corrosion Science 53, 873–885. [Google Scholar] [Crossref]
5. Zhihua, T., Shengtao, Z., Weihua, L., and Baorong, H. (2009). Corrosion inhibition of mild steel in acidic solution by some oxo-triazole derivatives. Corrosion Science 51, 2588–2595 doi:10.1016/j.corsci.2009.06.042. [Google Scholar] [Crossref]
6. Moretti, G., Guidi, F., Fabris, F. (2013). Corrosion inhibition of the mild steel in 0.5M HCl by 2-butyl-hexahydropyrrolo[1,2-b][1,2] oxazole. Corrosion Science 76, 206–218. https://dx.doi.org/10.1016/j.corsci.2013.06.044. [Google Scholar] [Crossref]
7. Naziru, A. M., Khalid, D. K., and Kolo, A.M. (2015). Corrosion inhibition of methanol extract of Parkia biglobosa Pulp on Carbon Steel in Acidic Medium. International Journal of Emerging Trends in Science and Technology. 2 (7) 2060 – 2064. [Google Scholar] [Crossref]
8. Oguzie, E.E., Enenebeaku, C.K., Akalezi, C.O., Okoro, S.C., Ayuk, A.A., and Ejike, E.N. (2010). Adsorption and corrosion-inhibiting effect of Dacryodis edulis extract on low-carbon-steel corrosion in acidic media. J. Colloid and Interface Sci. 349(1): 238-292. [Google Scholar] [Crossref]
9. Nomozov, A.K., Eshkaraev, S.C., Jumaeva, Z.E., Todjiev, J.N., Eshkoraev, S.S., Umirqulova, F.A. (2024). Experimental and Theoretical Studies of Salsola oppositifolia Extract as a Novel Eco-Friendly Corrosion Inhibition for Carbon Steel in 3% NaCl. International Journal of Engineering Trends and Technology, vol 72(9) pp. 312-320. [Google Scholar] [Crossref]
10. Quraishib, M.A., Ambrish, S., Vinod, K. S., Dileep, K. Y., Ashish, K.S. (2010). Green approach to corrosion inhibition of mild steel in hydrochloric acid and sulphuric acid solutions by the extract of Murraya koenigii leaves. Material Chemistry and Physics 122: pp.114–122. doi:10.1016/j.matchemphys.2010.02.066. [Google Scholar] [Crossref]
11. Lingjie, Li., Xueping, Z., Jinglei, L., Jianxin, H., Shengta. Z., Fusheng. P. (2012). Adsorption and corrosion inhibition of Osmanthus fragran leaves extract on carbon steel. Corrosion Science 63: pp. 82–90. http://dx.doi.org/10.1016/j.corsci.2012.05.026 [Google Scholar] [Crossref]
12. Iheaturu, N.C., Stanley, U.O., Bibiana, C. A., Magdalene, N. A., Daniel, I. U., Kayode, O. A., Augusta, N. E., Blessing, O. O., Precious, O. N., Chikaodinaka, N.U. (2024). Bio‑inhibitive corrosion effect of Carica papaya leaf extract on cold‑rolled mild steel in 0.1 M HCl Solution Journal of Engineering and Applied Science. 71: 203 https://doi.org/10.1186/s44147-024-00538-z. [Google Scholar] [Crossref]
13. Behpoura, M., Ghoreishia, S.M., Khayatkashani, M., Soltani, N. (2012). Green approach to corrosion inhibition of mild steel in two acidic solutions by the extract of Punica granatum peel and main constituents. Materials Chemistry and Physics. 131: 621– 633. doi:10.1016/j.matchemphys.2011.10.027 [Google Scholar] [Crossref]
14. Xianghong, L., Shuduan, D., Hui, F. (2012). Inhibition of the corrosion of steel in HCl, H2SO4 solutions by bamboo leaf extract Corrosion Science 62: pp 63–175. http://dx.doi.org/10.1016/j.corsci.2012.05.008. [Google Scholar] [Crossref]
15. Sunday, J.O. (2016). Gravimetric and electrochemical studies of corrosion inhibition potential of acid and ethanol extract of Siam weed on mild steel Leonardo. Journal of Sciences 29, 25-42. [Google Scholar] [Crossref]
16. Mustapha, R.K., Adoum, O.A., Rabil, A.K. (2022). Qualitative, quantitative phytochemical screening and antioxidant study of leaf and stem bark extract of Lannea microcarpa and Terminalia aviccinniodes. Bayero journal of pure and Applied Sciences. vol 13(1) 2006-6996. [Google Scholar] [Crossref]
17. Said, A., Rachid, H., Driss, C., Hamid, E., Zaki. S., Nuha, W., Avni, B., Arianit, R., Najat, H. (2022). Investigation of Two Corrosion Inhibitors in Acidic Medium Using Weight Loss, Electrochemical Study, Surface Analysis, and Computational Calculation. Journal of Bio- and Tribo-Corrosion. 8:86 https://doi.org/10.1007/s40735-022-00684-y. [Google Scholar] [Crossref]
18. Nwoye, C.I., and Nwigwe, U.S. (2025). Novel Green Corrosion Inhibitor for Mild Steel Protection in an Alkaline Environment. Portugaliae Electrochimica Acta 43: 11-22. [Google Scholar] [Crossref]
19. Jay, P.R. (2024). Corrosion Inhibition of Mild Steel in Hydrochloric Acid Solution using Methanolic Extracts of Elsholtzia communis and Spilanthes acmella as Green Inhibitors. Asian journal of Chemistry, vol 36(9), pp. 2129-2138. [Google Scholar] [Crossref]
20. Loto, A.C., Loto, R.T., Oshogbunu, J.O. (2016). Corrosion inhibition effect of Allium sativum extract on mild steel in HCl and H2SO4. Journal of Chemical and Pharmaceautical Research, 8(2): 216-230 [Google Scholar] [Crossref]
21. Odiongenyi, A.O., Odoemelam, S.A., Eddy, N.O. (2009). Corrision inhibition and adsorption properties of ethanol extract of Vemonia amygdalina for the corrosion of mild steel in H2SO4. Portugaliae Electrochem. Acta.27: 34-45. [Google Scholar] [Crossref]
22. Matthew, A.A., Samson, O.A., Adebowale, D.O., Oluwatosin, O.A., Joshua, I.O., and Enobong, F.D. (2021). Equilibrium and Thermodynamic Characteristics of the Corrosion Inhibition of Mild Steel Using Sweet Prayer Leaf Extract in Alkaline Medium. Progress in Chemical and Biochemical Research. 4(1): 80-91 [Google Scholar] [Crossref]
23. Iloamaeke, I.M., Egwuatu, C.I., Umeobika, U.C., Edike, H., Ohaekenyem, E.C. (2015). Corrosion inhibition and adsorption studies of ethanol extract of senna alata for mild steel in 2.0M H2SO4 Solution. International journal of materials chemistry and physics, vol 1(3), pp.295-299 [Google Scholar] [Crossref]
Metrics
Views & Downloads
Similar Articles
- Exploring the Concept of Generative Artificial Intelligence: A Narrative Review
- Design, Development, and Evaluation of a Critiquing-Based Mobile-Web Employment Recommender System
- Integrating Bhagavad Gita Principles with Modern Supply Chain Management: A Framework for Ethical and Resilient Operations
- Soilless Indoor Farming: A Systematic Review of Iot-Based Monitoring Systems and Physiochemical Characterization Methods for Lactuca Sativa
- Financial Awareness: A Survey of Students in Bhopal